TECHNOLOGY DESCRIPTION
ARI's thermochemical conversion technology (TCCT)
is a mobile, aboveground treatment system capable
of destroying organic compounds and immobilizing metals
and radionuclides present in soil, sediment, sludge,
liquid, and demolition debris. TCCT has demonstrated
effectiveness in treating poly-chlorinated biphenyls
(PCBs) and asbestos-containing material (ACM). ARI
is currently permitted to process ACM at its facility
in Tacoma, Washington.
TCCT
involves heating contaminated media in a rotary hearth
furnace. This process results in pyrolyzation of organic
materials and removal/immobilization of metals. Metals
and radionuclides that are not volatile at processing
temperatures (e.g., chromium, barium, uranium, and
plutonium) are immobilized as the metals are incorporated
into the molecular structure of the remineralized,
inert product. More volatile metals (e.g., lead, arsenic,
and cesium) may undergo partial volatilization. A
high efficiency wet scrubber removes volatilized metals
in the off-gas. TCCT is similar to vitrification but
does not involve complete melting. Instead, the process
results in sintering of the material.
Pyrolysis
of organic compounds takes place in the rotary hearth.
The pyrolysis products are directed via an induced
draft to a thermal oxidation unit that destroys any
residual organic contamination that might be present
in the off-gas. From the thermal oxidizer, the off-gases
are cooled and scrubbed for particulates and acid
components that might be present.
Wastes that are suitable for treatment using TCCT
include soil, ACM, liquids, sediment, sludge and demolition
debris. The full-scale TCCT system can treat 25 tons
of waste per day. Volume reduction of waste can range
from 10% to over 90% depending on the waste.
Following
a series of demonstrations at the Puget Sound Naval
Shipyard (PSNSY), the U.S. Environmental Protection
Agency (U.S. EPA) National Program Chemicals Division
issued ARI a National Mobile Operating Permit under
the Toxic Substance Control Act (TSCA). This permit
facilitates the use of the technology anywhere in
the U.S. or it's territories for the destruction of
PCBs. The U.S. EPA does not classify TCCT as incineration.
Under Washington State Department of Ecology Rules
(WAC 173-303-071), ARI can also perform treatability
studies at its Tacoma facility on up to 10,000 kg
of wastes containing other types of waste.
TECHNOLOGY
MERITS
TCCT costs are competitive to incineration costs because
the end product (produced from remineralization) is
expected to meet land disposal requirements. Thereby,
waste disposal costs will be reduced substantially.
Also, the rotary hearth does not agitate the waste
like a rotary kiln resulting in significantly less
particulate. TCCT is less expensive than vitrification
because processing temperatures are significantly
lower, resulting in lower energy costs, and because
costs associated with handling molten waste are not
incurred.
The
technical merits of TCCT are summarized as follows: